Palladium catalysts on amino-modified silica in application to the hydrogenation of p-nitroaniline

Palladium catalysts on amino-modified silica in application to the hydrogenation of p-nitroaniline Научная публикация

Журнал

Reaction Kinetics, Mechanisms and Catalysis
ISSN: 1878-5204 , E-ISSN: 1878-5190

Вых. Данные

Год: 2025, DOI: 10.1007/s11144-025-03013-9

Авторы

Latypova Adele R. ¹ , Goncharenko Alexandr A. ² , Lebedev Maxim D. ² , D’yakonov Vladimir A. ¹

Организации

1	Center for Advanced Catalytic Processes, N.D. Zelinsky Institute of Organic Chemistry, Moscow, 119991, Russia
2	Department of Inorganic Chemistry, Ivanovo State University of Chemistry and Technology, Ivanovo, 153000, Russia

In the context of this study, particular emphasis is placed on the identification of regularities in the influence of the number of amino groups and the particle size of functionalized silica, selected as a support for palladium nanoparticles, on the activity of the catalyst in the hydrogenation reaction of p-nitroaniline (p-NA). The study demonstrated that increasing the content of amino groups on the silica surface to achieve maximum activity necessitates the utilization of silica with a substantial particle size to ensure the maintenance of optimal distribution density of amino groups. This, in turn, enhances the activity of palladium in the liquid-phase hydrogenation of p-nitroaniline. A novel methodology for synthesizing core–shell particles of the Ni@SiO2 type has been developed.

Latypova A.R. , Goncharenko A.A. , Lebedev M.D. , D’yakonov V.A.
Palladium catalysts on amino-modified silica in application to the hydrogenation of p-nitroaniline
Reaction Kinetics, Mechanisms and Catalysis. 2025. DOI: 10.1007/s11144-025-03013-9 WOS Scopus OpenAlex

Web of science:	WOS:001613226000001
Scopus:	2-s2.0-105021522664
OpenAlex:	W4416146232

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