Synthesis and Structure of Bismuth(III) Chloride Complexes With 4,5‐Diphenyl‐1 H ‐Imidazole‐2(3 H )‐Thiones

Synthesis and Structure of Bismuth(III) Chloride Complexes With 4,5‐Diphenyl‐1 H ‐Imidazole‐2(3 H )‐Thiones Научная публикация

Журнал

ChemistrySelect
ISSN: 2365-6549

Вых. Данные

Год: 2026, Том: 11, Номер: 1, Номер статьи : e04023, Страниц : DOI: 10.1002/slct.202504023

Авторы

Baranov Vladimir V. ¹ , Nelyubina Yulia V. ² , Strelenko Yuri A. ¹ , Vinogradov Dmitry B. ¹ , Kravchenko Angelina N. ¹

Организации

1	Russian Academy of Sciences N. D. Zelinsky Institute of Organic Chemistry Moscow Russian Federation
2	Russian Academy of Sciences Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry Moscow region Russian Federation

Информация о финансировании (1)

The complexes cis-Cl, cis-μ-Cl, cis-LS1 [(LS1)2BiCl2(μ2-Cl)]2 (1), cis-Cl, cis-μ-Cl, trans-LS2 [(LS2)2BiCl2(μ2-Cl)]2 (2), [(LS3)3BiCl3] (3) and trans-Cl, cis-μ-Cl, cis-LS3 {[(LS3)2BiCl2(μ-Cl)]n} (4) were obtained for the first time. Their synthesis was carried out by reactions of 1,3-dimethyl-(LS1), 1,3-diethyl-(LS2) and 1-methyl-4,5-diphenyl-1H-Imidazole-2(3H)-thione (LS3) with BiCl3. The novel procedures of synthesis for ligands LS1- LS3 were used. The LS2 ligand was synthesized for the first time. The composition of the complexes was determined using elemental analysis, 1H, 13C NMR and IR spectroscopy. X-ray diffraction analysis for complexes 1,2 and 4 was performed. The formation of two types of dimeric complexes 1 and 2 with different mutual arrangement of ligands relative to the bismuth center has been revealed. A new type of a corner-sharing polymer complex 4 was discovered.

Baranov V.V. , Nelyubina Y.V. , Strelenko Y.A. , Vinogradov D.B. , Kravchenko A.N.
Synthesis and Structure of Bismuth(III) Chloride Complexes With 4,5‐Diphenyl‐1 H ‐Imidazole‐2(3 H )‐Thiones
ChemistrySelect. 2026. V.11. N1. e04023 . DOI: 10.1002/slct.202504023 WOS Scopus OpenAlex

Web of science:	WOS:001653133300001
Scopus:	2-s2.0-105026506126
OpenAlex:	W7118119614

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