Synthesis of functionalized hydroxymethylene-containing bisorganophosphorus acids

Synthesis of functionalized hydroxymethylene-containing bisorganophosphorus acids Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2024, Volume: 74, Number: 6, Pages: 1822-1837 Pages count : 16 DOI: 10.1007/s11172-024-4667-y

Authors

Bubnov Yu.N. ^1,2 , Prishchenko A.A. ³ , Livantsov M.V. ³ , Novikova O.P. ³ , Livantsova L.I. ³ , Baranin S.V. ²

Affiliations

1	A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Build. 1, 28 ul. Vavilova, 119991, Moscow, Russian Federation
2	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation
3	Chemical Department, M. V. Lomonosov Moscow State University, Build. 3, 1 Leninskiye Gory, 119991, Moscow, Russian Federation

Convenient syntheses of functionalized bisorganophosphorus acids and their derivatives containing hydroxymethylene moieties have been developed. Trimethylsilyl esters of trivalent phosphorus acids react with acyl chlorides to give new hydroxymethylene-substituted functionalized bisorganophosphorus acids containing P—C—P units. The resulting compounds are structural analogs of pharmaceutical agents used to treat various diseases. They are also of interest as promising biologically active substances and effective polydentate ligands.

Bubnov Y.N. , Prishchenko A.A. , Livantsov M.V. , Novikova O.P. , Livantsova L.I. , Baranin S.V.
Synthesis of functionalized hydroxymethylene-containing bisorganophosphorus acids
Russian Chemical Bulletin. 2024. V.74. N6. P.1822-1837. DOI: 10.1007/s11172-024-4667-y WOS Scopus OpenAlex

≡ Web of science:	WOS:001526885000022
≡ Scopus:	2-s2.0-105010635907
≡ OpenAlex:	W4412154483