The Effect of Proton Donors on the Process of Electrochemical Generation of Thiocyanogen and Its Reactivity

The Effect of Proton Donors on the Process of Electrochemical Generation of Thiocyanogen and Its Reactivity Full article

Journal

Russian Journal of Electrochemistry
ISSN: 1023-1935 , E-ISSN: 1608-3342

Output data

Year: 2024, Volume: 60, Number: 12, Pages: 1028-1040 Pages count : 13 DOI: 10.1134/s1023193524700575

Authors

Kozyrev Y.N. ¹ , Mendkovich A.S. ¹ , Kokorekin V.A. ^2,1 , Luzhkov V.B. ^3,4 , Rusakov A.I. ⁵ , Jouikov V.V. ⁶

Affiliations

1	Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia
2	Sechenov First Moscow State Medical University (Sechenov University), Moscow, Russia
3	Department of Fundamental Physico-Chemical Engineering, Lomonosov Moscow State University, Moscow, Russia
4	Federal Research Center of Problems of Chemical Physics and Medicinal Chemistry, Russian Academy of Sciences, Chernogolovka, Russia
5	Demidov Yaroslavl State University, Yaroslavl, Russia
6	UMR 6226-ISCR, University of Rennes, Rennes, France

In continuation of our systematic study of the mechanism of thiocyanogen generation via electrochemical oxidation of thiocyanate anion in acetonitrile, the influence of proton donors both on the generation and on the reactivity of thiocyanogen itself was studied by experimental (cyclic voltammetry, electrolysis) and theoretical (digital simulations, quantum chemical calculations) methods. In a series of acids of various strengths (acetic, trifluoroacetic and perchloric acids), the effect was revealed only in the case of a strong proton donor, perchloric acid. It was shown that perchloric acid forms with thiocyanogen a hydrogen-bonded complex, less active in the thiocyanation reaction.

Kozyrev Y.N. , Mendkovich A.S. , Kokorekin V.A. , Luzhkov V.B. , Rusakov A.I. , Jouikov V.V.
The Effect of Proton Donors on the Process of Electrochemical Generation of Thiocyanogen and Its Reactivity
Russian Journal of Electrochemistry. 2024. V.60. N12. P.1028-1040. DOI: 10.1134/s1023193524700575 WOS Scopus OpenAlex

Web of science:	WOS:001436402400003
Scopus:	2-s2.0-85219606704
OpenAlex:	W4408088419

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