Hexahydro-1,3,5-triazine-based synthesis of functionalized phosphorus-substituted dialkylamides of organophosphorus acids

Hexahydro-1,3,5-triazine-based synthesis of functionalized phosphorus-substituted dialkylamides of organophosphorus acids Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2024, Volume: 73, Number: 12, Pages: 3647-3657 Pages count : 11 DOI: 10.1007/s11172-024-4475-4

Authors

Bubnov Yu.N. ^1,2 , Prishchenko A.A. ³ , Livantsov M.V. ³ , Novikova O.P. ³ , Livantsova L.I. ³ , Baranin S.V. ²

Affiliations

1	A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Build. 1, 28 ul. Vavilova, 119991, Moscow, Russian Federation
2	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation
3	Chemical Department, M. V. Lomonosov Moscow State University, Build. 3, 1 Leninskiye Gory, 119991, Moscow, Russian Federation

Convenient synthesis of functionalized phosphorus-substituted dialkylamides of organophosphorus acids based on 1,3,5-trisubstituted hexahydro-1,3,5-triazines has been developed, and key aminomethylphosphonates containing NSi and NH moieties have been obtained. These compounds are convenient synthons for the synthesis of the target phosphorus-substituted amides of phosphorus acids containing P—C—N—P and P—C—N—C—C—N—P units. The resulting substances bear bioactive aminomethyl and thiophosphoryl moieties, have potential biological activity, and are also of interest as effective extractants and polydentate chelating ligands.

Bubnov Y.N. , Prishchenko A.A. , Livantsov M.V. , Novikova O.P. , Livantsova L.I. , Baranin S.V.
Hexahydro-1,3,5-triazine-based synthesis of functionalized phosphorus-substituted dialkylamides of organophosphorus acids
Russian Chemical Bulletin. 2024. V.73. N12. P.3647-3657. DOI: 10.1007/s11172-024-4475-4 WOS Scopus OpenAlex

≡ Web of science:	WOS:001427974500005
≡ Scopus:	2-s2.0-86000026604
≡ OpenAlex:	W4407792954