Synthesis of P(O)CH2N-substituted bis- and tris-phosphorus-containing amines

Synthesis of P(O)CH2N-substituted bis- and tris-phosphorus-containing amines Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2024, Volume: 73, Number: 10, Pages: 2974-2986 Pages count : 13 DOI: 10.1007/s11172-024-4415-3

Authors

Prishchenko A.A. ¹ , Livantsov M.V. ¹ , Novikova O.P. ¹ , Livantsova L.I. ¹ , Baranin S.V. ²

Affiliations

1	M. V. Lomonosov Moscow State University, Chemical Department, Build. 3, 1 Leninskiye Gory, 119991, Moscow, Russian Federation
2	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation

Convenient synthesis of P(O)CH2N-substituted bis- and tris-phosphorus-containing amines using two- and three-component systems have been developed. Methods for the synthesis of new bis- and tris-aminomethylating reagents are presented. Esters of trivalent phosphorus acids react with paraformaldehyde, alkylamines or N-substituted bis(alkoxymethyl)amines, as well as tris(butoxymethyl)amine to give new P(O)CH2N-substituted bis- and tris-phosphorus-containing amines. The resulting compounds are of interest as water-soluble polydentate ligands and effective extractants, as well as promising biologically active substances.

Prishchenko A.A. , Livantsov M.V. , Novikova O.P. , Livantsova L.I. , Baranin S.V.
Synthesis of P(O)CH2N-substituted bis- and tris-phosphorus-containing amines
Russian Chemical Bulletin. 2024. V.73. N10. P.2974-2986. DOI: 10.1007/s11172-024-4415-3 WOS Scopus OpenAlex

≡ Web of science:	WOS:001372605000028
≡ Scopus:	2-s2.0-85211323892
≡ OpenAlex:	W4405036683