Studying the Electrochemical Behavior of a Smooth Gold Electrode in a Solution of Bridged 1,2,4-Trioxalane in Acetonitrile

Studying the Electrochemical Behavior of a Smooth Gold Electrode in a Solution of Bridged 1,2,4-Trioxalane in Acetonitrile Full article

Journal

Russian Journal of Physical Chemistry A
ISSN: 0036-0244 , E-ISSN: 1531-863X

Output data

Year: 2024, Volume: 98, Number: 13, Pages: 3220-3226 Pages count : 7 DOI: 10.1134/s0036024424702443

Authors

Polyakov M.V. ¹ , Vedenyapina M.D. ¹ , Skundin A.M. ² , Yaremenko I.A. ¹ , Radulov P.S. ¹

Affiliations

1	Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia
2	Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071, Moscow, Russia

Cyclic voltammetry and gravimetry are used to study the behavior of a smooth gold electrode in a medium of bridged 1,2,4-trioxalane in acetonitrile. It is found that the peroxide bond in the molecule of bridged 1,2,4-trioxalane is reduced on the surface of the electrode during the cathodic process, with the subsequent formation of a diketone fragment. The formation of colloidal gold particles is detected during anodic oxidation.

Polyakov M.V. , Vedenyapina M.D. , Skundin A.M. , Yaremenko I.A. , Radulov P.S.
Studying the Electrochemical Behavior of a Smooth Gold Electrode in a Solution of Bridged 1,2,4-Trioxalane in Acetonitrile
Russian Journal of Physical Chemistry A. 2024. V.98. N13. P.3220-3226. DOI: 10.1134/s0036024424702443 WOS Scopus OpenAlex

Web of science:	WOS:001400872500030
Scopus:	2-s2.0-85218102596
OpenAlex:	W4406524653

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OpenAlex	1
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Web of science	1