Synthesis of functionalized PCHN-containing amines and their derivatives

Synthesis of functionalized PCHN-containing amines and their derivatives Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2025, Volume: 74, Number: 9, Pages: 2884-2900 Pages count : 17 DOI: 10.1007/s11172-025-4768-2

Authors

Bubnov Yu.N. ^1,2 , Prishchenko A.A. ³ , Livantsov M.V. ³ , Novikova O.P. ³ , Livantsova L.I. ³ , Baranin S.V. ²

Affiliations

1	A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Build. 1, 28 ul. Vavilova, 119991, Moscow, Russian Federation
2	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation
3	Chemical Department, M. V. Lomonosov Moscow State University, Build. 3, 1 Leninskiye Gory, 119991, Moscow, Russian Federation

Convenient syntheses of functionalized PCHNH-containing amines have been developed based on the nucleophilic addition of trivalent phosphorus acid esters to various imines. Subsequent acylation of these amines at the NH fragment opens the way to promising types of amides and sulfonamides of functionalized aminomethyl-substituted organophosphorus acids. The resulting compounds contain polar amide (sulfonylamide) and phosphoryl moieties, have potential biological activity, and are also of interest as effective extractants and polydentate chelating ligands.

Bubnov Y.N. , Prishchenko A.A. , Livantsov M.V. , Novikova O.P. , Livantsova L.I. , Baranin S.V.
Synthesis of functionalized PCHN-containing amines and their derivatives
Russian Chemical Bulletin. 2025. V.74. N9. P.2884-2900. DOI: 10.1007/s11172-025-4768-2 WOS Scopus

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≡ Scopus:	2-s2.0-105019333292