Electrochemical Reduction of Spirocyclopentylmalonyl Peroxide in an Aqueous Medium

Electrochemical Reduction of Spirocyclopentylmalonyl Peroxide in an Aqueous Medium Full article

Journal

Russian Journal of Physical Chemistry A
ISSN: 0036-0244 , E-ISSN: 1531-863X

Output data

Year: 2020, Volume: 94, Number: 4, Pages: 859-863 Pages count : 5 DOI: 10.1134/s0036024420040238

Authors

Vedenyapina M.D. ¹ , Skundin A.M. ² , Vil V.A. ¹ , Kazakova M.M. ¹ , Barsegyan Ya.A. ¹

Affiliations

1	Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia
2	Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, Russia

The electrochemical reduction of spirocyclopentylmalonyl peroxide in an aqueous medium is studied via cyclic voltammetry on a gold stationary electrode. Based on calculations using parameters of cyclic voltammetry recorded at different scan rates, it is concluded that the studied material underwent two successive one-electron reductions, and a scheme is proposed for its cathodic reduction.

Vedenyapina M.D. , Skundin A.M. , Vil V.A. , Kazakova M.M. , Barsegyan Y.A.
Electrochemical Reduction of Spirocyclopentylmalonyl Peroxide in an Aqueous Medium
Russian Journal of Physical Chemistry A. 2020. V.94. N4. P.859-863. DOI: 10.1134/s0036024420040238 WOS Scopus OpenAlex

Web of science:	WOS:000526987400029
Scopus:	2-s2.0-85083495492
OpenAlex:	W3016286984

DB	Citing
OpenAlex	4
Scopus	3