Synthesis and properties of energetic N-fluorodinitromethyl heterocyclic salts

Synthesis and properties of energetic N-fluorodinitromethyl heterocyclic salts Full article

Journal

Journal of Fluorine Chemistry
ISSN: 1873-3328 , E-ISSN: 0022-1139

Output data

Year: 2025, Volume: 285-286, Article number : 110436, Pages count : DOI: 10.1016/j.jfluchem.2025.110436

Authors

Gakh Andrei A. ^1,2 , Semenov Victor V. ³

Affiliations

1	The Discovery Chemistry Project, Bethesda, MD 20814, USA
2	The University of Virginia, Charlottesville, VA 22908, USA
3	N. D. Zelinsky Institute of Organic Chemistry RAS, 119991 Moscow, Russian Federation

The synthesis of a new class of energetic salts, N-fluorodinitromethyl heterocyclic salts, was accomplished by electrophilic fluorination of corresponding heterocyclic N-dinitromethyl ylides with diluted fluorine. These salts represent rare examples of compounds containing a fluorodinitromethyl moiety directly attached to a positively charged nitrogen atom. Further improvements can be achieved in combination with explosophoric anions, such as the cyanodinitromethanide anion. Despite their unusual structural features, N-fluorodinitromethyl heterocyclic salts have good thermal and chemical stability under ambient conditions.

Gakh A.A. , Semenov V.V.
Synthesis and properties of energetic N-fluorodinitromethyl heterocyclic salts
Journal of Fluorine Chemistry. 2025. V.285-286. 110436 . DOI: 10.1016/j.jfluchem.2025.110436 WOS Scopus OpenAlex

Web of science:	WOS:001508640600001
Scopus:	2-s2.0-105007057647
OpenAlex:	W4410760673

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