Sciact
  • EN
  • RU

Investigation of the reaction of hexafluoro-1,4-naphthoquinone with substituted phenols Научная публикация

Журнал Journal of Fluorine Chemistry
ISSN: 1873-3328 , E-ISSN: 0022-1139
Вых. Данные Год: 2025, Том: 282, Номер статьи : 110402, Страниц : DOI: 10.1016/j.jfluchem.2025.110402
Авторы Kudryavtseva Ekaterina N. 1 , Lichitsky Boris V. 1 , Tretyakov Evgeny V. 1
Организации
1 N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Leninsky Pr. 47, Moscow 119991, Russian Federation

Реферат: Reaction of hexafluoro-1,4-naphthoquinone with various phenols was studied for the first time. It was shown that sodium acetate is a convenient reagent for implementation of the process. The investigated condensation led exclusively to substitution of two fluorine atoms in the quinone core. Based on performed research the method for preparation of substituted 2,3-diaryloxy-5,6,7,8-tetrafluoronaphthalene-1,4-diones was elaborated. Using similar conditions pentafluorobenzo[a]phenoxazine derivatives were obtained from 2-aminophenols. In contrast to phenols cyclic 1,3-diketones in the reaction with perfluoronaphthoquinone act as C-nucleophiles resulting in fluorinated polycondensed furans. Structures of key obtained products were proved using X-ray analysis.
Библиографическая ссылка: Kudryavtseva E.N. , Lichitsky B.V. , Tretyakov E.V.
Investigation of the reaction of hexafluoro-1,4-naphthoquinone with substituted phenols
Journal of Fluorine Chemistry. 2025. V.282. 110402 . DOI: 10.1016/j.jfluchem.2025.110402 WOS Scopus OpenAlex
Даты:
Поступила в редакцию: 13 янв. 2025 г.
Опубликована online: 12 февр. 2025 г.
Идентификаторы БД:
Web of science: WOS:001426617100001
Scopus: 2-s2.0-85217436797
OpenAlex: W4407401637
Цитирование в БД:
БД Цитирований
OpenAlex Нет цитирований
Scopus Нет цитирований
Альметрики: