Synthesis and Structures of Organogold 4,4,5,5-Tetramethyl-4,5-Dihydroimidazole-3-Oxide-1-Oxyl Derivatives Stabilized by Phosphine Ligands

Synthesis and Structures of Organogold 4,4,5,5-Tetramethyl-4,5-Dihydroimidazole-3-Oxide-1-Oxyl Derivatives Stabilized by Phosphine Ligands Full article

Journal

Journal of Structural Chemistry
ISSN: 1573-8779 , E-ISSN: 0022-4766

Output data

Year: 2025, Volume: 66, Number: 12, Pages: 2652-2664 Pages count : 13 DOI: 10.1134/s0022476625120170

Authors

Zayakin I.A. ¹ , Nasyrova D.I. ¹ , Korlyukov A.A. ² , Bagryanskaya I.Yu. ³ , Minyaev M.E. ¹ , Shangin P.G. ¹ , Syroeshkin M.A. ¹ , Tretyakov E.V. ¹

Affiliations

1	Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia
2	Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia
3	Vorozhtsov Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

Organogold derivatives of nitronyl nitroxide, stabilized by phosphine ligands are obtained. Conformational features of the phosphine ligands and nitronyl nitroxide nuclei are analyzed by single crystal X-ray diffraction. Effective π–π stacking interactions are detected and described for the first time in the crystals of organogold derivatives.

Zayakin I.A. , Nasyrova D.I. , Korlyukov A.A. , Bagryanskaya I.Y. , Minyaev M.E. , Shangin P.G. , Syroeshkin M.A. , Tretyakov E.V.
Synthesis and Structures of Organogold 4,4,5,5-Tetramethyl-4,5-Dihydroimidazole-3-Oxide-1-Oxyl Derivatives Stabilized by Phosphine Ligands
Journal of Structural Chemistry. 2025. V.66. N12. P.2652-2664. DOI: 10.1134/s0022476625120170 WOS OpenAlex

Submitted:	Oct 18, 2025
Published online:	Jan 10, 2026

Web of science:	WOS:001659042800008
OpenAlex:	W7121514763

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