Selective C5–H Bromination of 4-Amino-1,3-diarylimidazolium Salts | Sciact

Selective C5–H Bromination of 4-Amino-1,3-diarylimidazolium Salts Научная публикация

Журнал

Russian Journal of Organic Chemistry
ISSN: 1608-3393 , E-ISSN: 1070-4280

Вых. Данные

Год: 2025, Том: 61, Номер: 11, Страницы: 2084-2089 Страниц : 6 DOI: 10.1134/s1070428025604145

Авторы

Shepelenko K.E. ^1,2 , Shevchenko M.A. ² , Minyaev M.E. ³ , Yatsenko A.N. ^1,2 , Chernyshev V.M. ^1,2

Организации

1	Platov South-Russian State Polytechnical University, 346428, Novocherkassk, Russia
2	Skolkovo Institute of Science and Technology, Skolkovo Innovation Center, 121205, Moscow, Russia
3	Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

A method for the synthesis of 4-amino-5-bromo-1,3-diarylimidazolium salts is developed. The approach involves the selective bromination of 4-amino-1,3-diarylimidazolium salts using bromomalononitrile as a mild brominating agent. The subsequent functionalization of these products is demonstrated via reaction of the amino group with electrophilic reagents.

Shepelenko K.E. , Shevchenko M.A. , Minyaev M.E. , Yatsenko A.N. , Chernyshev V.M.
Selective C5–H Bromination of 4-Amino-1,3-diarylimidazolium Salts
Russian Journal of Organic Chemistry. 2025. V.61. N11. P.2084-2089. DOI: 10.1134/s1070428025604145 WOS Scopus OpenAlex

Поступила в редакцию:	1 окт. 2025 г.
Опубликована online:	14 янв. 2026 г.

≡ Web of science:	WOS:001661526800022
≡ Scopus:	2-s2.0-105027518056
≡ OpenAlex:	W7123497224