Development of new methods in modern selective organic synthesis: preparation of functionalized molecules with atomic precision

Development of new methods in modern selective organic synthesis: preparation of functionalized molecules with atomic precision Научная публикация

Журнал

Russian Chemical Reviews
ISSN: 1468-4837 , E-ISSN: 0036-021X

Вых. Данные

Год: 2014, Том: 83, Номер: 10, Страницы: 885-985 Страниц : 101 DOI: 10.1070/rc2014v083n10abeh004471

Авторы

Ananikov Valentin Pavlovich ^1,2 , Khemchyan Levon L ¹ , Ivanova Yu V ¹ , Bukhtiyarov Valerii Ivanovich ^3,4 , Sorokin A M ³ , Prosvirin I P ³ , Vatsadze Sergey Zurabovich ⁵ , Medved'ko A V ⁵ , Nuriev V N ⁵ , Dilman Alexander D ¹ , Levin Vitalij V ¹ , Koptyug Igor Valentinovich ^6,4 , Kovtunov K V ^6,4 , Zhivonitko V V ^6,4 , Likholobov Vladimir Alexandrovich ⁷ , Romanenko Anatoly Vladimirovich ³ , Simonov P A ^3,4 , Nenajdenko Valentin Georgievich ^5,8 , Shmatova O I ⁵ , Muzalevskiy V M ⁵ , Nechaev M S ^5,9 , Asachenko A F ⁹ , Morozov O S ⁹ , Dzhevakov P B ⁹ , Osipov Sergey N ⁸ , Vorobyeva D V ⁸ , Topchiy M A ⁸ , Zotova M A ⁸ , Ponomarenko Sergey Anatol'evich ^5,10 , Borshchev O V ¹⁰ , Luponosov Y N ¹⁰ , Rempel A A ^11,12 , Valeeva A A ^11,12 , Stakheev Aleksandr Yurevich ¹ , Turova Olga Vasil'evna ¹ , Mashkovsky I S ¹ , Sysolyatin Sergey Viktorovich ¹³ , Malykhin V V ¹³ , Bukhtiyarova G A ³ , Terent'ev Alexander Olegovich ¹ , Krylov I B ¹

Организации

1	N D Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
2	St Petersburg State University
3	G.K.Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences
4	Novosibirsk State University
5	Department of Chemistry, Lomonosov Moscow State University
6	The Institute International Tomography Center of the Siberian Branch of the Russian Academy of Sciences (ITC SB RAS)
7	Institute of Hydrocarbons Processing. IHP SB RAS
8	Institute of Organoelement Compounds, Russian Academy of Sciences
9	A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences
10	Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences
11	Institute of Solid State Chemistry, Ural Branch of the Russian Academy of Sciences
12	Ural Federal University named after the First President of Russia B.N.Yeltsin
13	Institute for Problems of Chemical and Energetic Technologies, Siberian Branch of the Russian Academy of Science

The challenges of the modern society and the growing demand of high-technology sectors of industrial production bring about a new phase in the development of organic synthesis. A cutting edge of modern synthetic methods is introduction of functional groups and more complex structural units into organic molecules with unprecedented control over the course of chemical transformation. Analysis of the state-of-the-art achievements in selective organic synthesis indicates the appearance of a new trend — the synthesis of organic molecules, biologically active compounds, pharmaceutical substances and smart materials with absolute selectivity. Most advanced approaches to organic synthesis anticipated in the near future can be defined as ‘atomic precision’ in chemical reactions. The present review considers selective methods of organic synthesis suitable for transformation of complex functionalized molecules under mild conditions. Selected key trends in the modern organic synthesis are considered including the preparation of organofluorine compounds, catalytic cross-coupling and oxidative cross-coupling reactions, atom-economic addition reactions, methathesis processes, oxidation and reduction reactions, synthesis of heterocyclic compounds, design of new homogeneous and heterogeneous catalytic systems, application of photocatalysis, scaling up synthetic procedures to industrial level and development of new approaches to investigation of mechanisms of catalytic reactions.

Ananikov V.P. , Khemchyan L.L. , Ivanova Y.V. , Bukhtiyarov V.I. , Sorokin A.M. , Prosvirin I.P. , Vatsadze S.Z. , Medved'ko A.V. , Nuriev V.N. , Dilman A.D. , Levin V.V. , Koptyug I.V. , Kovtunov K.V. , Zhivonitko V.V. , Likholobov V.A. , Romanenko A.V. , Simonov P.A. , Nenajdenko V.G. , Shmatova O.I. , Muzalevskiy V.M. , Nechaev M.S. , Asachenko A.F. , Morozov O.S. , Dzhevakov P.B. , Osipov S.N. , Vorobyeva D.V. , Topchiy M.A. , Zotova M.A. , Ponomarenko S.A. , Borshchev O.V. , Luponosov Y.N. , Rempel A.A. , Valeeva A.A. , Stakheev A.Y. , Turova O.V. , Mashkovsky I.S. , Sysolyatin S.V. , Malykhin V.V. , Bukhtiyarova G.A. , Terent'ev A.O. , Krylov I.B.
Development of new methods in modern selective organic synthesis: preparation of functionalized molecules with atomic precision
Russian Chemical Reviews. 2014. V.83. N10. P.885-985. DOI: 10.1070/rc2014v083n10abeh004471 OpenAlex

Анаников В.П. , Хемчян Л.Л. , Иванова Ю.В. , Бухтияров В.И. , Сорокин А.М. , Просвирнин И.П. , Вацадзе С.З. , Медведько А.В. , Нуриев В.Н. , Дильман А.Д. , Левин В.В. , Коптюг И.В. , Ковтунов К.В. , Живонитко В.В. , Лихолобов В.В. , Романенко А.В. , Симонов П.А. , Ненайденко В.Г. , Шматова О.И. , Музалевский В.М. , Нечаев М.С. , Асаченко А.Ф. , Морозов О.С. , Джеваков П.Б. , Осипов С.Н. , Воробьева Д.В. , Топчий М.А. , Зотова М.А. , Пономаренко С.А. , Борщев О.В. , Лупоносов Ю.Н. , Ремпель А.А. , Валеева А.А. , Стахеев А.Ю. , Турова О.В. , Машковский И.С. , Сысолятин С.В. , Малыхин В.В. , Бухтиярова Г.А. , Терентьев А.О. , Крылов И.Б.
Развитие методологии современного селективного органического синтеза: получение функционализированных молекул с атомарной точностью
Успехи химии. 2014. Т.83. №10. С.885-985. DOI: 10.1070/RC2014v083n10ABEH004471?locatt=label:RUSSIAN

Поступила в редакцию:	30 мая 2014 г.
Опубликована online:	8 сент. 2014 г.

≡ OpenAlex:

W4243668163