Highly Selective Catalytic Synthesis of (E,E)-1,4-Diiodobuta-1,3-diene via Atom-Efficient Addition of Acetylene and Iodine: A Versatile (E,E)-1,3-Diene Building Block in Cross-Coupling Reactions

Highly Selective Catalytic Synthesis of (E,E)-1,4-Diiodobuta-1,3-diene via Atom-Efficient Addition of Acetylene and Iodine: A Versatile (E,E)-1,3-Diene Building Block in Cross-Coupling Reactions Научная публикация

Журнал

Synlett
ISSN: 0936-5214 , E-ISSN: 1437-2096

Вых. Данные

Год: 2011, Том: 2011, Номер: 14, Страницы: 2021-2024 Страниц : 4 DOI: 10.1055/s-0030-1261166

Авторы

Ananikov Valentine P ¹ , Beletskaya Irina P ³ , Kashin Alexey S ¹ , Hazipov Oleg V ^1,2 , Starikova Zoya A ⁴

Организации

1	Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences
2	Litvinenko Institute of Physical Organic and Coal Chemistry, National Academy of Sciences
3	Chemistry Department, Lomonosov Moscow State University
4	Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences

The first practical procedure is reported for the synthesis of (E,E)-1,4-diiodobuta-1,3-diene from very simple starting materials (acetylene and I2). A pure crystalline product was obtained in a green chemical procedure utilizing the key advantages of highly selective Pt-catalyzed transformation and 100% atom efficiency of the addition reaction. The Pt catalyst was recovered and re-used in the reaction without a noticeable loss of activity.

Ananikov V.P. , Beletskaya I.P. , Kashin A.S. , Hazipov O.V. , Starikova Z.A.
Highly Selective Catalytic Synthesis of (E,E)-1,4-Diiodobuta-1,3-diene via Atom-Efficient Addition of Acetylene and Iodine: A Versatile (E,E)-1,3-Diene Building Block in Cross-Coupling Reactions
Synlett. 2011. V.2011. N14. P.2021-2024. DOI: 10.1055/s-0030-1261166 WOS Scopus OpenAlex

Поступила в редакцию:	16 мая 2011 г.
Опубликована online:	10 авг. 2011 г.

≡ Web of science:	WOS:000294161400014
≡ Scopus:	2-s2.0-80052076923
≡ OpenAlex:	W1988067013