Hydrogenation of plant polyalkoxybenzene derivatives: convenient access to coenzyme Q0 analogues

Hydrogenation of plant polyalkoxybenzene derivatives: convenient access to coenzyme Q0 analogues Full article

Journal

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Output data

Year: 2020, Volume: 30, Number: 5, Pages: 599-601 Pages count : 3 DOI: 10.1016/j.mencom.2020.09.015

Authors

Varakutin Alexander E. ¹ , Muravsky Egor A. ² , Shinkarev Ilia Yu. ² , Khrustalev Victor N. ^1,3 , Semenov Victor V. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation
2	D. I. Mendeleev University of Chemical Technology of Russia, 125047 Moscow, Russian Federation
3	Peoples Friendship University of Russia (RUDN University), 117198 Moscow, Russian Federation

A technologically advanced protocol has been developed for converting plant allyl(polyalkoxy)benzenes to methyl- and propyl(polyalkoxy)benzenes being intermediates in the syntheses of coenzyme Q0 analogues. The key stage of allyl and benzaldehyde moieties hydrogenation was carried out in a periodical autoclave mode on highly porous ceramic block Pd-catalysts. These catalysts possess large surface area, low hydraulic resistance, significant thermal and mechanical stabililty, multiple cycling and easy regeneration, which can dramatically reduce Pd consumption.

Varakutin A.E. , Muravsky E.A. , Shinkarev I.Y. , Khrustalev V.N. , Semenov V.V.
Hydrogenation of plant polyalkoxybenzene derivatives: convenient access to coenzyme Q0 analogues
Mendeleev Communications. 2020. V.30. N5. P.599-601. DOI: 10.1016/j.mencom.2020.09.015 WOS Scopus OpenAlex

Web of science:	WOS:000577530900015
Scopus:	2-s2.0-85092445433
OpenAlex:	W3090261126

DB	Citing
OpenAlex	7
Scopus	4
Web of science	5