Electrochemical Behavior of Tricyclic Monoperoxide in an Acetonitrile Solution on Smooth Gold

Electrochemical Behavior of Tricyclic Monoperoxide in an Acetonitrile Solution on Smooth Gold Full article

Journal

Russian Journal of Physical Chemistry A
ISSN: 0036-0244 , E-ISSN: 1531-863X

Output data

Year: 2026, Volume: 100, Number: 1, Pages: 141-147 Pages count : 7 DOI: 10.1134/s0036024425703133

Tags

cyclic voltammetry, peroxides, cathodic reduction, anodic oxidation, gold corrosion

Authors

Polyakov M.V. ¹ , Vedenyapina M.D. ¹ , Skundin A.M. ² , Yaremenko I.A. ^3,1 , Radulov P.S. ¹

Affiliations

1	Zelinskii Institute of Organic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia
2	Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071, Moscow, Russia
3	Mendeleev University of Chemical Technology of Russia, 125047, Moscow, Russia

The electrochemical behavior of tricyclic monoperoxide on a smooth gold electrode in an acetonitrile solution was studied by cyclic voltammetry (CV). It was found that the cathodic process involves the joint transfer of two electrons. In the anodic process, the electrode corrodes, forming gold nanoparticles. A mechanism for the reduction of monoperoxide to triketone was proposed.

Polyakov M.V. , Vedenyapina M.D. , Skundin A.M. , Yaremenko I.A. , Radulov P.S.
Electrochemical Behavior of Tricyclic Monoperoxide in an Acetonitrile Solution on Smooth Gold
Russian Journal of Physical Chemistry A. 2026. V.100. N1. P.141-147. DOI: 10.1134/s0036024425703133

Submitted:	Aug 6, 2025
Accepted:	Aug 27, 2025
Published online:	Mar 6, 2026

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