Synthesis of CaSn(OH)6 by Ultrasonic Dispersion

Synthesis of CaSn(OH)6 by Ultrasonic Dispersion Full article

Journal

Physics of Wave Phenomena
ISSN: 1541-308X

Output data

Year: 2026, Volume: 34, Number: 2, Pages: 150-160 Pages count : 10 DOI: 10.3103/S1541308X26700044

Tags

sonocrystallization, CaSn(OH)6, morphology, cavitation, X-ray powder diffraction, scanning electron microscopy, sizes of crystallites

Authors

Azarov K.V. ^1,2 , Mashchenko N.V. ¹ , Bogdan T.V. ^1,3 , Bogorodskiy S.E. ¹ , Skiba M.A. ¹ , Bogdan L.V. ^1,4 , Lukyanov P.S. ^1,3 , Bogdan V.I. ¹

Affiliations

1	Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 119991 Russia
2	Faculty of Chemical Technology and Ecology, Gubkin Russian State University of Oil and Gas, Moscow, 119991 Russia
3	Department of Chemistry, Lomonosov Moscow State University, Moscow, 119991 Russia
4	Department of Biology, Lomonosov Moscow State University, Moscow, 119991 Russia

The influence of ultrasonic dispersion power on the morphology, texture characteristics, and phase composition of CaSn(OH)6 samples synthesized by salt coprecipitation has been studied. The samples were characterized using X-ray diffraction analysis, scanning electron microscopy, and low-temperature nitrogen adsorption. The specific surface area of the samples is found to depend nonlinearly on the radiation power. Linear interpolation and Voigt fitting [1] were used to determine the linear sizes of crystallites according to the Scherrer principle [2]. The Keller–Miksis model [3] was used to calculate the critical bubble size at different impact powers and determine the “hot point” temperature at the instant of bubble collapse. It is shown that ultrasonic processing with a power density of 33 W/cm2 provides the highest collapse temperature at the smallest sizes of cavitation bubble (548 μm); in this case, the CaSn(OH)6 phase undergoes decomposition with the formation of calcium hydroxide Ca(OH)2 and amorphous tin oxide SnO2.

Azarov K.V. , Mashchenko N.V. , Bogdan T.V. , Bogorodskiy S.E. , Skiba M.A. , Bogdan L.V. , Lukyanov P.S. , Bogdan V.I.
Synthesis of CaSn(OH)6 by Ultrasonic Dispersion
Physics of Wave Phenomena. 2026. V.34. N2. P.150-160. DOI: 10.3103/S1541308X26700044

Submitted:	Aug 28, 2025
Accepted:	Nov 18, 2025

No identifiers