Beyond Phosphorus: Diazaadamantane and Bispidine Analogs of RAPTA-C and RAED-C

Beyond Phosphorus: Diazaadamantane and Bispidine Analogs of RAPTA-C and RAED-C Full article

Journal

Journal of Structural Chemistry
ISSN: 1573-8779 , E-ISSN: 0022-4766

Output data

Year: 2026, Volume: 67, Number: 3, Pages: 520-531 Pages count : 12 DOI: 10.1134/s0022476626030054

Authors

Medved′ko A.V. ¹ , Troshin I.A. ^2,1 , Minyaev M.E. ¹ , Vatsadze S.Z. ¹

Affiliations

1	Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia
2	MIREA - Russian Technological University, Moscow, Russia

Half sandwich ruthenium complexes with 5,7-dimethyl-1,3-diazaadamantane-6-one, 5,7-dimethyl-1,3-diazaadamantane, 1,5-dimethyl-3,7-diazabicyclo[3.3.1]nonan-9-one, and 1,5-dimethyl-3,7-diazabicyclo [3.3.1]nonane are prepared for the first time; their crystal structures are determined by single crystal XRD. It is established that 5,7-dimethyl-1,3-diazaadamantane can form both mononuclear and dinuclear complexes with ruthenium. In the bispidine complexes, hydrogen atoms at the nitrogen atoms are oriented at a non-typical angle.

Medved′ko A.V. , Troshin I.A. , Minyaev M.E. , Vatsadze S.Z.
Beyond Phosphorus: Diazaadamantane and Bispidine Analogs of RAPTA-C and RAED-C
Journal of Structural Chemistry. 2026. V.67. N3. P.520-531. DOI: 10.1134/s0022476626030054 WOS Scopus OpenAlex

Медведько А.В. , Трошин И.А. , Миняев М.Е. , Вацадзе С.З.
Не только фосфор: диазаадамантановые и биспидиновые аналоги RAPTA-C и RAED-C
Журнал структурной химии. 2026. Т.67. №3. 161738 . DOI: 10.26902/jsc_id161738 OpenAlex

Submitted:	Dec 2, 2025
Published online:	Apr 10, 2026

≡ Web of science:	WOS:001737907400011
≡ Scopus:	2-s2.0-105036050100
≡ OpenAlex:	W7153040135