Synthesis of functionalized 1,2-bis(phosphoryl)propanes and their analogs

Synthesis of functionalized 1,2-bis(phosphoryl)propanes and their analogs Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2026, Volume: 75, Number: 2, Pages: 601-608 Pages count : 8 DOI: 10.1007/s11172-026-4914-5

Authors

Bubnov Yu.N. ^1,2 , Prishchenko A.A. ² , Livantsov M.V. ³ , Novikova O.P. ³ , Livantsova L.I. ³ , Baranin S.V. ²

Affiliations

1	A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Build. 1, 28 ul. Vavilova, 119991, Moscow, Russian Federation
2	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation
3	Chemical Department, M. V. Lomonosov Moscow State University, Build. 3, 1 Leninskiye Gory, 119991, Moscow, Russian Federation

Convenient syntheses of functionalized 1,2-bis(phosphoryl)propanes and their analogs, containing P—C(C—N)—C—P units, based on phosphonoacetic ester, allyl bromide, and epichlorohydrin have been developed. The addition of diethyl phosphite to intermediate 1-(dialkylaminomethyl)vinylphosphonates affords new target products in high yields. The resulting compounds are structural analogs of amino carboxylic acids and natural pyrophosphates and are of interest as promising bioactive substances, water-soluble polydentate ligands, and effective extractants.

Bubnov Y.N. , Prishchenko A.A. , Livantsov M.V. , Novikova O.P. , Livantsova L.I. , Baranin S.V.
Synthesis of functionalized 1,2-bis(phosphoryl)propanes and their analogs
Russian Chemical Bulletin. 2026. V.75. N2. P.601-608. DOI: 10.1007/s11172-026-4914-5 WOS Scopus OpenAlex

Бубнов Ю.Н. , Прищенко А.А. , Ливанцов М.В. , Новикова О.П. , Ливанцова Л.И. , Баранина С.В.
Синтез функционализированных 1,2-бисфосфорилпропанов и их аналогов
Известия Академии наук. Серия химическая. 2026. Т.75. №2. С.601-608.

Submitted:	Jul 7, 2025
Published online:	Apr 11, 2026

≡ Web of science:	WOS:001738024100006
≡ Scopus:	2-s2.0-105036036043
≡ OpenAlex:	W7153543960