New Stannylenes Based on Bulky Silyl-Substituted 2,6-bis(2’-Hydroxyphenyl)Pyridine Ligands: When Size Does Matter

New Stannylenes Based on Bulky Silyl-Substituted 2,6-bis(2’-Hydroxyphenyl)Pyridine Ligands: When Size Does Matter Научная публикация

Журнал

Journal of Organometallic Chemistry
ISSN: 1872-8561 , E-ISSN: 0022-328X

Вых. Данные

Год: 2026, Том: 1057, Номер статьи : 124201, Страниц : DOI: 10.1016/j.jorganchem.2026.124201

Авторы

Serova Valeriia A. ¹ , Teplova Kamella R. ¹ , Mankaev Badma N. ¹ , Agaeva Milana U. ¹ , Lyssenko Konstantin A. ¹ , Egorov Mikhail P. ² , Syroeshkin Mikhail A. ² , Karlov Sergey S. ¹

Организации

1	Chemistry Department, Lomonosov Moscow State University, 119991 Moscow, Russia
2	N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russia

The reaction of Lappert's stannylene, Sn[N(SiMe3)2]2, with novel sterically hindered 2,6-bis(2-hydroxyphenyl)pyridine ligands bearing trimethylsilyl (1a) or triphenylsilyl (1b) groups yielded the corresponding stannylene complexes 2a and 2b The molecular structures of both complexes were determined by X-ray diffraction analysis. While complex 2b adopts a monomeric structure in the solid state, complex 2a forms a centrosymmetric dimer stabilized by an unusually long and weak intermolecular Sn···Sn contact (3.6817(4) Å). NMR spectroscopy confirmed the monomeric structure of both compounds in solution. The electrochemical and UV/Vis properties of the stannylenes were investigated, revealing a significant solvent-dependent behavior. A topological analysis of the electron density (QTAIM) within the framework of Bader's "Atoms in Molecules" theory was performed to elucidate the nature of the non-covalent interactions that stabilize the dimer of 2a.

Serova V.A. , Teplova K.R. , Mankaev B.N. , Agaeva M.U. , Lyssenko K.A. , Egorov M.P. , Syroeshkin M.A. , Karlov S.S.
New Stannylenes Based on Bulky Silyl-Substituted 2,6-bis(2’-Hydroxyphenyl)Pyridine Ligands: When Size Does Matter
Journal of Organometallic Chemistry. 2026. V.1057. 124201 . DOI: 10.1016/j.jorganchem.2026.124201 OpenAlex

Поступила в редакцию:	18 сент. 2025 г.
Опубликована online:	30 мая 2026 г.

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