Synthesis and properties of duplicate 6,6'-linkered 1,5-diazabicyclo[3.1.0]hexanes

Synthesis and properties of duplicate 6,6'-linkered 1,5-diazabicyclo[3.1.0]hexanes Научная публикация

Журнал

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Вых. Данные

Год: 2026, Том: 36, Номер статьи : 8037, Страниц : DOI: 10.71267/mencom.8037

Авторы

Khakimov D.V. ¹ , Kuznetsov V.V. ¹ , Dmitrenok A.S. ¹ , Goloveshkin A.S. ² , Samigullina A.I. ¹

Организации

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation
2	A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119334 Moscow, Russian Federation

A series of bi- and bis-1,5-diazabicyclo[3.1.0]hexanes connected by linkers through 6,6' positions were synthesized and characterized, their enthalpies of formation being high ranging within 50–115 kcal mol–1. For cyclohexane dispirotethered diazabicyclohexanes, an experimental density of 1.314 g cm–3 at 120 K was determined, which is one of the highest among related analogs. Model calculations of crystal packings were performed and compared with experimental data.

Khakimov D.V. , Kuznetsov V.V. , Dmitrenok A.S. , Goloveshkin A.S. , Samigullina A.I.
Synthesis and properties of duplicate 6,6'-linkered 1,5-diazabicyclo[3.1.0]hexanes
Mendeleev Communications. 2026. Т.36. 8037 . DOI: 10.71267/mencom.8037 OpenAlex

Поступила в редакцию:	10 мар. 2026 г.
Принята к публикации:	15 мая 2026 г.

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