(Cyclopropyl)(phenyl)sulfane Full article
| Journal |
Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285 |
||
|---|---|---|---|
| Output data | Year: 2026, Volume: 75, Number: 5, Pages: 1636-1640 Pages count : 5 DOI: 10.1007/s11172-026-5014-2 | ||
| Authors |
|
||
| Affiliations |
|
Abstract:
The decomposition of N-cyclopropyl-N-nitrosourea in the presence of sodium benzenethiolate was studied. The cyclopropyldiazonium intermediate formed as a result of S-azo coupling yields reactive N-(cyclopropylthio)diazenes, which decompose with the release of nitrogen via a radical pathway involving cyclopropyl and phenylsulfanyl radicals. Further transformations of these radicals are determined by the nature of the substrates used. Under optimal conditions, PhS• and C3H5• radicals are coupled to give (cyclopropyl)(phenyl)sulfane in 84% yield.
Cite:
Shulishov E.V.
, Menchikov L.G.
, Tomilov Y.V.
(Cyclopropyl)(phenyl)sulfane
Russian Chemical Bulletin. 2026. V.75. N5. P.1636-1640. DOI: 10.1007/s11172-026-5014-2 WOS Scopus OpenAlex
(Cyclopropyl)(phenyl)sulfane
Russian Chemical Bulletin. 2026. V.75. N5. P.1636-1640. DOI: 10.1007/s11172-026-5014-2 WOS Scopus OpenAlex
Original:
Шулишов Е.В.
, Менчиков Л.Г.
, Томилов Ю.В.
(Фенил)(циклопропил)сульфан
Известия Академии наук. Серия химическая. 2026. Т.75. №5. С.1636-1639.
(Фенил)(циклопропил)сульфан
Известия Академии наук. Серия химическая. 2026. Т.75. №5. С.1636-1639.
Dates:
| Published online: | Aug 3, 2026 |
Identifiers:
| ≡ Web of science: | WOS:001839451500028 |
| ≡ Scopus: | 2-s2.0-105046368708 |
| ≡ OpenAlex: | W7172329090 |