Synthesis and structure of 1-(dimethoxyphosphoryl)-2-phenylcyclopropanecarboxamide

Synthesis and structure of 1-(dimethoxyphosphoryl)-2-phenylcyclopropanecarboxamide Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2026, Volume: 75, Number: 8, Pages: 2657-2661 Pages count : 5 DOI: 10.1007/s11172-026-5112-1

Tags

donor-acceptor cyclopropanes; radical phosphorylation; cinnamamides; the Corey—Chaykovsky reaction

Authors

Kuleshov A.V. ¹ , Lapa G.B. ^1,2 , Ignatieva E.M. ¹ , Trushkov I.V. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation
2	N. I. Pirogov Russian National Research Medical University, Build. 6, 1 ul. Ostrovityanova, 117513, Moscow, Russian Federation

A donor-acceptor cyclopropane containing carbamoyl and dimethoxyphosphoryl groups as acceptor substituents was fi rst synthesized by a simple two-step procedure involving radical phosphorylation of cinnamamide followed by the Corey—Chaykovsky cyclopropanation of the resulting alkene.

Kuleshov A.V. , Lapa G.B. , Ignatieva E.M. , Trushkov I.V.
Synthesis and structure of 1-(dimethoxyphosphoryl)-2-phenylcyclopropanecarboxamide
Russian Chemical Bulletin. 2026. V.75. N8. P.2657-2661. DOI: 10.1007/s11172-026-5112-1

Submitted:	Apr 14, 2026
Accepted:	Jun 21, 2026
Published online:	Oct 17, 2026

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