Convenient synthesis of furo[2,3-c][1,2]dioxoles from 1-aryl-2-allylalkane-1,3-diones

Convenient synthesis of furo[2,3-c][1,2]dioxoles from 1-aryl-2-allylalkane-1,3-diones Full article

Journal

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Output data

Year: 2020, Volume: 30, Number: 5, Pages: 607-609 Pages count : 3 DOI: 10.1016/j.mencom.2020.09.018

Authors

Zdvizhkov Alexander T. ¹ , Radulov Peter S. ² , Novikov Roman A. ² , Tafeenko Viktor A. ³ , Chernyshev Vladimir V. ^4,3 , Ilovaisky Alexey I. ² , Terent’ev Alexander O. ² , Nikishin Gennady I. ²

Affiliations

1	Interbranch Engineering Center ‘Composites of Russia’, Bauman Moscow State Technical University, 105005 Moscow, Russian Federation
2	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation
3	Department of Chemistry, M. V. Lomonosov Moscow State University, 119991 Moscow, Russian Federation
4	A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, 119071 Moscow, Russian Federation

Treatment of 1-aryl-2-allylalkane-1,3-diones with I2/H2O2 system in the presence of catalytic amount of phosphomolybdic acid affords furo[2,3-c][1,2]dioxole derivatives. With other acidic catalysts such as BF3 · Et2O, SnCl4, H2SO4 or TsOH, mixtures with linear 4-acyloxy-2,5-diiodoalkan-1-ones are formed.

Zdvizhkov A.T. , Radulov P.S. , Novikov R.A. , Tafeenko V.A. , Chernyshev V.V. , Ilovaisky A.I. , Terent’ev A.O. , Nikishin G.I.
Convenient synthesis of furo[2,3-c][1,2]dioxoles from 1-aryl-2-allylalkane-1,3-diones
Mendeleev Communications. 2020. V.30. N5. P.607-609. DOI: 10.1016/j.mencom.2020.09.018 WOS Scopus OpenAlex

Web of science:	WOS:000577530900018
Scopus:	2-s2.0-85092063889
OpenAlex:	W3089459228

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