Реферат: Herewith, we present another facet of the versatile catalytic reactivity of bulky bis-amino-bis-pyridylmethyl Mn complexes: besides highly enantioselective (up to 99% ee) epoxidation, benzhydryl-substituted Mn catalysts have been found to convert olefinic substrates into the products of syn-addition to the C═C bond, hydroxy-carboxylates, that can prevail under certain conditions. The mechanism of syn-hydroxy-acyloxylation is discussed, with the data obtained providing evidence in favor of the so far lacking direct enantioselective OH and OC(O)R transfer from the high-valent Mn active species to the olefinic C═C group. Such a mechanism is conceptually reminiscent of Rieske dioxygenases that catalyze enantioselective 1,2-dihydroxylation of C═C bonds, simultaneously incorporating two cis-ligands from the reactive metal center into the resulting diol in a syn-selective fashion.

Библиографическая ссылка: Sherstyuk V.A. , Ottenbacher R.V. , Talsi E.P. , Bryliakov K.P.
Asymmetric Epoxidation vs syn-Hydroxy-Acyloxylation of Olefins in the Presence of Sterically Demanding Nonheme Manganese Complexes
ACS Catalysis. 2024. V.14. N1. P.498-507. DOI: 10.1021/acscatal.3c04832 WOS Scopus OpenAlex

Идентификаторы БД:

Web of science:	WOS:001137558600001
Scopus:	2-s2.0-85181805299
OpenAlex:	W4390114514

Цитирование в БД:

БД	Цитирований
OpenAlex	3
Scopus	4
Web of science	2

Альметрики: