Synthesis of new pyrido[3,2-b][1,4]benzoxazines and -benzothiazines

Synthesis of new pyrido[3,2-b][1,4]benzoxazines and -benzothiazines Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2022, Volume: 71, Number: 1, Pages: 126-130 Pages count : 5 DOI: 10.1007/s11172-022-3385-6

Authors

Starosotnikov A.M. ¹ , Ivanova V.V. ^2,1 , Klimova T.A. ¹ , Kolotyrkina N.G. ¹ , Bastrakov M.A. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russian Federation
2	Dmitry Mendeleev University of Chemical Technology of Russia, Moscow, Russian Federation

New pyrido[3,2-b][1,4]benzoxazines and pyrido[3,2-b][1,4]benzothiazines were synthesized by the base-mediated reactions of substituted 2-chloro-3-nitropyridines with o-amino(thio)phenols. The reactions involve a sequential nucleophilic substitution of the chlorine atom and the nitro group affected by either O,N- or S,N-binucleophile. In the case of aminothiophenols, the reaction proceeded via substitution of the chlorine atom followed by the Smiles rearrangement, and an intramolecular substitution of the nitro group by S-nucleophile.

Starosotnikov A.M. , Ivanova V.V. , Klimova T.A. , Kolotyrkina N.G. , Bastrakov M.A.
Synthesis of new pyrido[3,2-b][1,4]benzoxazines and -benzothiazines
Russian Chemical Bulletin. 2022. V.71. N1. P.126-130. DOI: 10.1007/s11172-022-3385-6 WOS Scopus OpenAlex

Web of science:	WOS:000755136000016
Scopus:	2-s2.0-85124973171
OpenAlex:	W4213005941

DB	Citing
OpenAlex	8
Scopus	8
Web of science	8