Реферат: Mechanical and thermal hazards are critical for chemical compounds. Foremost, the design of novel energetic materials that are stable, insensitive, but have a detonation performance superior to in-service materials is of great interest. However, a single source of safety data for hazardous materials with explosophoric functionalities is still missing. Herein, an experimental database on thermal stability, impact, and friction sensitivity for 150 CHNOFCl compounds is presented. Mechanical sensitivity is discussed in detail: particle size and shape effects, instrument design, and experimental protocol are considered. The entire dataset was analyzed using the simple descriptors of molecular structure. Mechanical sensitivity was found to be linearly correlated with the maximal heat of explosion for certain classes of compounds (nitrobenzenes, furazans, pyrazoles, etc.). Consideration of all species shows that previously proposed sensitivity increase with an energy content rise is relevant, although it is not strict line, as was assumed, but rather a widened “strip”. A new parameter, safety factor, is proposed to combine two types of sensitivity data. With this factor, the limiting values of mechanical sensitivity at a given energy content are provided that represent the state-of-art development of energetic materials and may be used for screening and design of novel compounds.

Библиографическая ссылка: Muravyev N.V. , Meerov D.B. , Monogarov K.A. , Melnikov I.N. , Kosareva E.K. , Fershtat L.L. , Sheremetev A.B. , Dalinger I.L. , Fomenkov I.V. , Pivkina A.N.
Sensitivity of energetic materials: Evidence of thermodynamic factor on a large array of CHNOFCl compounds
Chemical Engineering Journal. 2021. V.421. 129804 . DOI: 10.1016/j.cej.2021.129804 WOS Scopus OpenAlex

Идентификаторы БД:

Web of science:	WOS:000664196000005
Scopus:	2-s2.0-85105325794
OpenAlex:	W3155397476

Цитирование в БД:

БД	Цитирований
OpenAlex	147
Web of science	133
Scopus	142

Альметрики: