Electrochemical Generation of Peroxy Radicals and Subsequent Peroxidation of 1,3-Dicarbonyls in an Undivided Cell

Electrochemical Generation of Peroxy Radicals and Subsequent Peroxidation of 1,3-Dicarbonyls in an Undivided Cell Научная публикация

Журнал

Organic Letters
ISSN: 1523-7060 , E-ISSN: 1523-7052

Вых. Данные

Год: 2024, Том: 26, Номер: 1, Страницы: 166–171 Страниц : DOI: 10.1021/acs.orglett.3c03780

Авторы

Bityukov Oleg V. ^1,2 , Skokova Ksenia V. ^1,2 , Vil’ Vera A. ^1,2 , Nikishin Gennady I. ² , Terent’ev Alexander O. ^1,2

Организации

1	All-Russian Research Institute for Phytopathology B. Vyazyomy, Moscow Region 143050, Russian Federation
2	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prospekt, Moscow, 119991, Russian Federation

The generation of peroxy radicals from hydroperoxides with subsequent selective peroxidation of 1,3-dicarbonyls in an undivided electrochemical cell under constant current conditions is reported. The method provides a variety of peroxy-containing barbituric acids and 4-hydroxy-2(5H)-furanones with yields of up to 74%. Only the combination of anodic and cathodic processes provides efficient peroxidation by generating a set of alkoxy and peroxy radicals. NaNO3 acts as both an electrolyte and a redox mediator of radical reactions.

Bityukov O.V. , Skokova K.V. , Vil’ V.A. , Nikishin G.I. , Terent’ev A.O.
Electrochemical Generation of Peroxy Radicals and Subsequent Peroxidation of 1,3-Dicarbonyls in an Undivided Cell
Organic Letters. 2024. V.26. N1. P.166–171. DOI: 10.1021/acs.orglett.3c03780 WOS Scopus OpenAlex

Web of science:	WOS:001143377500001
Scopus:	2-s2.0-85181574426
OpenAlex:	W4390346976

БД	Цитирований
OpenAlex	5
Scopus	5