Oxime‐Derived Iminyl Radicals in Selective Processes of Hydrogen Atom Transfer and Addition to Carbon‐Carbon π‐Bonds Review
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Advanced Synthesis & Catalysis
ISSN: 1615-4169 , E-ISSN: 1615-4150 |
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| Output data | Year: 2021, Volume: 363, Number: 10, Pages: 2502-2528 Pages count : 27 DOI: 10.1002/adsc.202100058 | ||
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Abstract:
Oximes represent one of the fundamental organic compound classes with a wide range of synthetic applications. In the last decade O-substituted oximes were recognized as the synthetically available and versatile precursors of iminyl radicals via one-electron oxidation or one-electron reduction employing visible light photoredox catalysts, salts of abundant metals (such as Cu or Fe), or other convenient reagents. Iminyl radicals are powerful synthons for various processes of cyclization, ring-opening, CH-functionalization, and coupling. The present review is focused on the synthetic methods based on oxime-derived iminyl radicals developed in the last few years excluding ring opening reactions of cyclic iminyl radicals that were summarized in recent publications. The review consists of two main parts: (1) reactions of iminyl radicals involving 1,n-hydrogen atom transfer (n=5 in most cases) and (2) reactions involving the addition of iminyl radical to the carbon-carbon π-bond.
Cite:
Krylov I.B.
, Segida O.O.
, Budnikov A.S.
, Terent'ev A.O.
Oxime‐Derived Iminyl Radicals in Selective Processes of Hydrogen Atom Transfer and Addition to Carbon‐Carbon π‐Bonds
Advanced Synthesis & Catalysis. 2021. V.363. N10. P.2502-2528. DOI: 10.1002/adsc.202100058 WOS Scopus OpenAlex
Oxime‐Derived Iminyl Radicals in Selective Processes of Hydrogen Atom Transfer and Addition to Carbon‐Carbon π‐Bonds
Advanced Synthesis & Catalysis. 2021. V.363. N10. P.2502-2528. DOI: 10.1002/adsc.202100058 WOS Scopus OpenAlex
Identifiers:
| Web of science: | WOS:000637864300001 |
| Scopus: | 2-s2.0-85104029624 |
| OpenAlex: | W3142595670 |