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The Effect of Pressure on the Oxidative Dehydrogenation of Ethane with Molecular Oxygen over a MoVNbTeOx Mixed Oxide Catalyst Full article

Journal Russian Journal of Physical Chemistry B
ISSN: 1990-7923 , E-ISSN: 1990-7931
Output data Year: 2022, Volume: 16, Number: 7, Pages: 1267-1271 Pages count : 5 DOI: 10.1134/s1990793122070132
Authors Mishanin I.I. 1 , Bogdan V.I. 1
Affiliations
1 Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991, Moscow, Russia

Abstract: The process of oxidative dehydrogenation of ethane (ODE) at an elevated pressure over a MoVNbTeOx mixed oxide catalyst is studied. It is found that when the reaction is carried out at 280°C, the fraction of the total amount of reacted oxygen consumed for the formation of ethylene decreases from 100 to 68% with the increase in pressure from 0.1 to 10.0 MPa, which may indicate an increase in the role of chemisorbed oxygen in the ODE process at a high pressure. Here, the productivity with respect to ethylene at 280°C and 10.0 MPa is higher in comparison with the value obtained at 360°C and 0.1 MPa.
Cite: Mishanin I.I. , Bogdan V.I.
The Effect of Pressure on the Oxidative Dehydrogenation of Ethane with Molecular Oxygen over a MoVNbTeOx Mixed Oxide Catalyst
Russian Journal of Physical Chemistry B. 2022. V.16. N7. P.1267-1271. DOI: 10.1134/s1990793122070132 WOS Scopus OpenAlex
Identifiers:
Web of science: WOS:000920094600012
Scopus: 2-s2.0-85146756107
OpenAlex: W4317878218
Citing:
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OpenAlex 3
Scopus 3
Web of science 3
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