Synthesis of (4Z)-Unsaturated Iodo-δ-lactones by Catalytic Cross-Cyclomagnesiation

Synthesis of (4Z)-Unsaturated Iodo-δ-lactones by Catalytic Cross-Cyclomagnesiation Full article

Journal

Russian Journal of Organic Chemistry
ISSN: 1608-3393 , E-ISSN: 1070-4280

Output data

Year: 2022, Volume: 58, Number: 12, Pages: 1954-1958 Pages count : 5 DOI: 10.1134/s1070428022120259

Authors

Makarov A.A. ¹ , Ishbulatov I.V. ¹ , Makarova E.Kh. ¹ , D’yakonov V.A. ² , Dzhemilev U.M. ²

Affiliations

1	Institute of Petrochemistry and Catalysis, Ufa Federal Research Center, Russian Academy of Sciences, Ufa, 450075 Russia
2	Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 119991 Russia

6-[(4Z)-1-Iodoalk-4-en-1-yl]tetrahydropyran-2-ones (iodo-δ-lactone analogs) were synthesized for the first time from 5Z,9Z-alka-5,9-dienoic acids in three steps through Cp2TiCl2-catalyzed intermolecular cyclomagnesiation of aliphatic and oxygen-containing 1,2-dienes in the key step.

Makarov A.A. , Ishbulatov I.V. , Makarova E.K. , D’yakonov V.A. , Dzhemilev U.M.
Synthesis of (4Z)-Unsaturated Iodo-δ-lactones by Catalytic Cross-Cyclomagnesiation
Russian Journal of Organic Chemistry. 2022. V.58. N12. P.1954-1958. DOI: 10.1134/s1070428022120259 WOS Scopus OpenAlex

Web of science:	WOS:000933777000025
Scopus:	2-s2.0-85147759445
OpenAlex:	W4319598785

DB	Citing
OpenAlex	3
Scopus	2
Web of science	2