Aqueous phase hydrogenation of furfural to tetrahydrofurfuryl alcohol over Pd/UiO-66

Aqueous phase hydrogenation of furfural to tetrahydrofurfuryl alcohol over Pd/UiO-66 Full article

Journal

Catalysis Communications
ISSN: 1566-7367 , E-ISSN: 1873-3905

Output data

Year: 2021, Volume: 148, Article number : 106178, Pages count : DOI: 10.1016/j.catcom.2020.106178

Authors

Wang Chunhua ¹ , Wang Anjie ¹ , Yu Zhiquan ¹ , Wang Yao ¹ , Sun Zhichao ¹ , Kogan Victor M. ² , Liu Ying-Ya ¹

Affiliations

1	State Key Laboratory of Fine Chemicals, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, PR China
2	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow 119991, Russia

A Pd/UiO-66 catalyst was synthesized with well-dispersed Pd nanoparticles. The obtained catalyst was tested in the hydrogenation of furfural to tetrahydrofurfuryl alcohol in various solvents, Water was found to be the most suitable solvent. Pd/UiO-66 exhibited much higher activity than Pd/SiO2 and Pd/γ-Al2O3, completely converting furfural to tetrahydrofurfuryl alcohol with 100% selectivity under mild conditions. The hydrogenation of Cdouble bondO moiety in tetrahydrofurfural was rate-determining step. Static adsorption measurement indicated that the adsorption of furfural on UiO-66 was significantly stronger than that on SiO2 or γ-Al2O3, suggesting that the adsorption play an important role in the gas-liquid-solid furfural hydrogenation reaction.

Wang C. , Wang A. , Yu Z. , Wang Y. , Sun Z. , Kogan V.M. , Liu Y-Y.
Aqueous phase hydrogenation of furfural to tetrahydrofurfuryl alcohol over Pd/UiO-66
Catalysis Communications. 2021. V.148. 106178 . DOI: 10.1016/j.catcom.2020.106178 WOS Scopus OpenAlex

Web of science:	WOS:000591722600016
Scopus:	2-s2.0-85092020651
OpenAlex:	W3089472594

DB	Citing
OpenAlex	57
Web of science	47
Scopus	56