Benzo[1,2-d:4,5-d′]bis([1,2,3]thiadiazole)-4-carbonitrile

Benzo[1,2-d:4,5-d′]bis([1,2,3]thiadiazole)-4-carbonitrile Full article

Journal

Molbank
ISSN: 1422-8599

Output data

Year: 2023, Volume: 2023, Number: 3, Article number : M1683, Pages count : DOI: 10.3390/m1683

Authors

Chmovzh Timofey N. ^1,2 , Kudryashev Timofey A. ^3,1 , Gaisin Karim S. ^3,1 , Rakitin Oleg A. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry Russian Academy of Sciences, 47 Leninsky Prospekt, 119991 Moscow, Russia
2	Nanotechnology Education and Research Center, South Ural State University, 76 Lenina Avenue, 454080 Chelyabinsk, Russia
3	Department of Chemistry, Moscow State University, 119899 Moscow, Russia

Electron-withdrawing heterocyclic units are found in most organic optoelectronic materials. Benzo[1,2-d:4,5-d′]bis([1,2,3]thiadiazole) is an interesting new heterocyclic system, the chemical properties of which are much less studied than other fused thiadiazoles. Cyano derivatives of electron-accepting heterocycles are known as potential components of photoluminescent materials. In this communication, benzo[1,2-d:4,5-d′]bis([1,2,3]thiadiazole)-4-carbonitrile was successfully obtained via the cyanation of 4-bromobenzo[1,2-d:4,5-d′]bis([1,2,3]thiadiazole) with copper(I) cyanide in DMF. The structure of the newly synthesized compound was established by means of elemental analysis, high-resolution mass spectrometry, 1H and 13C NMR, and IR spectroscopy.

Chmovzh T.N. , Kudryashev T.A. , Gaisin K.S. , Rakitin O.A.
Benzo[1,2-d:4,5-d′]bis([1,2,3]thiadiazole)-4-carbonitrile
Molbank. 2023. V.2023. N3. M1683 . DOI: 10.3390/m1683 WOS Scopus OpenAlex

Web of science:	WOS:001076658800001
Scopus:	2-s2.0-85172788817
OpenAlex:	W4382982294

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