Terpolymerization of propylene oxide, carbon dioxide, and trimethylene carbonate

Terpolymerization of propylene oxide, carbon dioxide, and trimethylene carbonate Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2022, Volume: 71, Number: 8, Pages: 1770-1776 Pages count : 7 DOI: 10.1007/s11172-022-3588-x

Authors

Nysenko Z.N. ¹ , Said-Galiev E.E. ² , Nikiforova G.G. ² , Buzin M.I. ² , Glazkov A.A. ¹ , Il’in M.M. ² , Belyaev G.A. ¹ , Rusak V.V. ¹ , Sakharov A.M. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991 Мoscow, Russian Federation
2	A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991 Moscow, Russian Federation

High-molecular-weight polymers with different contents of propylene carbonate (PC), and trimethylene carbonate (TMC) units in the polymer chain were synthesized by the coordination anionic copolymerization of carbon dioxide, propylene oxide (PO), and TMC in supercritical carbon dioxide (scCO2). Zinc adipate (ZnAd) was used as a catalyst. The terpolymerization products were characterized by 1H and 13C NMR, IR spectroscopy, GPC, and DSC. The effect of the reaction conditions on the yield, composition, structure, and molecular weight and thermal characteristics of the terpolymers was studied. The phase behavior of the synthesized polymers and mixtures of polypropylene carbonate with polytrimethylene carbonate was examined.

Nysenko Z.N. , Said-Galiev E.E. , Nikiforova G.G. , Buzin M.I. , Glazkov A.A. , Il’in M.M. , Belyaev G.A. , Rusak V.V. , Sakharov A.M.
Terpolymerization of propylene oxide, carbon dioxide, and trimethylene carbonate
Russian Chemical Bulletin. 2022. V.71. N8. P.1770-1776. DOI: 10.1007/s11172-022-3588-x WOS Scopus OpenAlex

≡ Web of science:	WOS:000859732900022
≡ Scopus:	2-s2.0-85138672944
≡ OpenAlex:	W4296831801