Improved Synthesis and Thermochemical Properties of Amino- and Hydrazino-1,2,4,5-Tetrazines

Improved Synthesis and Thermochemical Properties of Amino- and Hydrazino-1,2,4,5-Tetrazines Full article

Journal

Chemistry of Heterocyclic Compounds
ISSN: 1573-8353 , E-ISSN: 0009-3122

Output data

Year: 2020, Volume: 56, Number: 11, Pages: 1449-1453 Pages count : 5 DOI: 10.1007/s10593-020-02836-9

Authors

Kon’kova Tat’yana S. ¹ , Matyushin Yurii N. ¹ , Miroshnichenko Evgeniy А. ¹ , Palysaeva Nadezhda V. ² , Sheremetev Aleksei B. ²

Affiliations

1	N.N. Semenov Federal Research Center for Chemical Physics Russian Academy of Sciences, Moscow, Russia.
2	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, Russia;

Improved protocols for the synthesis of 3,6-diamino- and 3,6-dihydrazino-1,2,4,5-tetrazines as well as 6-amino[1,2,4]triazolo[4,3-b]-[1,2,4,5]tetrazine were developed. Combustion energies were determined by the bomb calorimetry and the enthalpies of formation in the standard state were calculated for the compounds of this study. Based on the obtained data, the contribution of the 1,2,4,5-tetrazine moiety to the enthalpy of combustion of its derivatives was estimated.

Kon’kova T.S. , Matyushin Y.N. , Miroshnichenko E.А. , Palysaeva N.V. , Sheremetev A.B.
Improved Synthesis and Thermochemical Properties of Amino- and Hydrazino-1,2,4,5-Tetrazines
Chemistry of Heterocyclic Compounds. 2020. V.56. N11. P.1449-1453. DOI: 10.1007/s10593-020-02836-9 WOS Scopus OpenAlex

≡ Web of science:	WOS:000595400100001
≡ Scopus:	2-s2.0-85097015338
≡ OpenAlex:	W3109646980