Electron-deficient N-oxyl radicals – new reagents for selective oxidative functionalization of organic substrates

Electron-deficient N-oxyl radicals – new reagents for selective oxidative functionalization of organic substrates Full article

Journal

Journal of physics
ISSN: 1742-6596 , E-ISSN: 1742-6588

Output data

Year: 2021, Volume: 1942, Number: 1, Article number : 012007, Pages count : DOI: 10.1088/1742-6596/1942/1/012007

Authors

Krylov I B ^1,2 , Budnikov A S ¹ , Lopat’eva E R ^1,2 , Segida O O ¹ , Paveliev S A ¹ , Terent’ev A O ^1,2

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences, 47 Leninsky prosp., Moscow 119991, Russian Federation
2	Mendeleev University of Chemical Technology of Russia, 9 Miusskaya sq., Moscow 125047, Russian Federation

N-oxyl radicals are well known as one of the richest classes of long-living free radicals. They are widely used as redox catalysts, mediators of living polymerization, contrast reagents for tomography applications, spin labels for biomacromolecule studies, components of organic batteries and magnetic materials. In the last decade, less stable but more reactive electron-deficient N-oxyl radicals have been harnessed as reagents for oxidative functionalization of organic substrates via selective C-H bond cleavage or radical addition to C = C bonds. Wide array of C-O coupling products can be achieved employing N-oxyl radicals as O-reagents for oxidative C-O coupling. Selected examples of methods for oxidative functionalization of organic substrates by N-oxyl radicals developed in our group are summarized in the present paper.

Krylov I.B. , Budnikov A.S. , Lopat’eva E.R. , Segida O.O. , Paveliev S.A. , Terent’ev A.O.
Electron-deficient N-oxyl radicals – new reagents for selective oxidative functionalization of organic substrates
Journal of physics. 2021. V.1942. N1. 012007 . DOI: 10.1088/1742-6596/1942/1/012007 Scopus OpenAlex

Scopus:	2-s2.0-85117540277
OpenAlex:	W3174204423

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