Catalytic cyclopropanation of hexa-1,3,5-triene with diazomethane as a simple synthesis of high-energy tercyclopropane

Catalytic cyclopropanation of hexa-1,3,5-triene with diazomethane as a simple synthesis of high-energy tercyclopropane Full article

Journal

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Output data

Year: 2023, Volume: 33, Number: 4, Pages: 512-514 Pages count : 3 DOI: 10.1016/j.mencom.2023.06.023

Authors

Shulishov Evgeny V. ¹ , Pantyukh Olga A. ¹ , Menchikov Leonid G. ¹ , Tomilov Yury V. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation

A simple method for a preparing of tercyclopropane or 1,2-dicyclopropylethene by the catalytic cyclo-propanation of hexa-1,3,5-triene with diazomethane has been developed. Thermochemical characteristics for tercyclopropane show that it may be a candidate to replace syntin as a propellant for spacecraft engines.

Shulishov E.V. , Pantyukh O.A. , Menchikov L.G. , Tomilov Y.V.
Catalytic cyclopropanation of hexa-1,3,5-triene with diazomethane as a simple synthesis of high-energy tercyclopropane
Mendeleev Communications. 2023. V.33. N4. P.512-514. DOI: 10.1016/j.mencom.2023.06.023 WOS Scopus OpenAlex

≡ Web of science:	WOS:001044189600001
≡ Scopus:	2-s2.0-85166511831
≡ OpenAlex:	W4384501495