Composition and Structure of Complexes Formed in GeCl4–2-Hydroxybenzene(2-hydroxynaphthaline-1)carbaldehyde Isonicotinoylhydrazone–ZnCl2–Methanol

Composition and Structure of Complexes Formed in GeCl4–2-Hydroxybenzene(2-hydroxynaphthaline-1)carbaldehyde Isonicotinoylhydrazone–ZnCl2–Methanol Full article

Journal

Russian Journal of General Chemistry
ISSN: 1070-3632 , E-ISSN: 1608-3350

Output data

Year: 2020, Volume: 90, Number: 12, Pages: 2323-2327 Pages count : 5 DOI: 10.1134/s1070363220120154

Authors

Shmatkova N.V. ¹ , Seifullina I.I. ¹ , Skorokhod L.S. ¹ , Morozov A.N. ² , Popov L.D. ² , Gazieva G.A. ³

Affiliations

1	Mechnikov Odessa National University, Odessa, Ukraine
2	South Federal University, Rostov-on-Don, Russia
3	N. D. Zelinsky Institute of Organic Chemistry of the Russian Academy of Sciences, Moscow, Russia

Tetrachlorozincates [Ge(LH)2][ZnCl4]∙CH3OH were isolated for the first time from isonicotinoylhydrazone 2-hydroxybenzene (2-hydroxynaphyl-1)carbaldehyde (H2L)–GeCl4–ZnCl2–CH3OH systems, in which cations are [Ge(L·H)2]2+ complexes protonated by the pyridine nitrogen atom, with L ligands tridentately coordinated via the azomethine nitrogen atom and oxygen atoms of deprotonated hydroxyazino and hydroxy groups. The complexes were studied using the methods of conductometry, thermogravimetry, IR, and 1H NMR spectroscopy.

Shmatkova N.V. , Seifullina I.I. , Skorokhod L.S. , Morozov A.N. , Popov L.D. , Gazieva G.A.
Composition and Structure of Complexes Formed in GeCl4–2-Hydroxybenzene(2-hydroxynaphthaline-1)carbaldehyde Isonicotinoylhydrazone–ZnCl2–Methanol
Russian Journal of General Chemistry. 2020. V.90. N12. P.2323-2327. DOI: 10.1134/s1070363220120154 WOS Scopus OpenAlex

≡ Web of science:	WOS:000615262800015
≡ Scopus:	2-s2.0-85100594835
≡ OpenAlex:	W3127224782