Suzuki cross-coupling of hexachlorobenzene promoted by the Buchwald ligands

Suzuki cross-coupling of hexachlorobenzene promoted by the Buchwald ligands Full article

Journal

Russian Chemical Bulletin
ISSN: 1573-9171 , E-ISSN: 1066-5285

Output data

Year: 2022, Volume: 71, Number: 1, Pages: 169-172 Pages count : 4 DOI: 10.1007/s11172-022-3392-7

Authors

Vasil’ev A.A. ¹ , Burukin A.S. ¹ , Zhdankina G.M. ¹ , Zlotin S.G. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991 Moscow, Russian Federation

The study of cross-coupling between hexachlorobenzene and phenylboronic acid comprised five Buchwald ligands, from which 2-dicyclohexylphosphino-2′-(dimethylamino)biphenyl (DavePHOS) provided the best conversion. When excess of phenylboronic acid was used, a mixture of isomeric tri-, tetra- and pentaphenyl-substituted derivatives in the ∼10:70:20 ratio was obtained, along with minor amounts of hydrodechlorination products.

Vasil’ev A.A. , Burukin A.S. , Zhdankina G.M. , Zlotin S.G.
Suzuki cross-coupling of hexachlorobenzene promoted by the Buchwald ligands
Russian Chemical Bulletin. 2022. V.71. N1. P.169-172. DOI: 10.1007/s11172-022-3392-7 WOS Scopus OpenAlex

Web of science:	WOS:000755136000023
Scopus:	2-s2.0-85124466297
OpenAlex:	W4213283129

DB	Citing
OpenAlex	4
Scopus	4
Web of science	4