Convenient preparation of arylnitromethanes by oxidation of benzaldoximes with urea hydrogen peroxide

Convenient preparation of arylnitromethanes by oxidation of benzaldoximes with urea hydrogen peroxide Full article

Journal

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Output data

Year: 2021, Volume: 31, Number: 6, Pages: 818-820 Pages count : 3 DOI: 10.1016/j.mencom.2021.11.016

Authors

Maksimenko Anna S. ¹ , Koblov Ivan A. ¹ , Chernysheva Natalia B. ¹ , Kislyi Victor P. ¹ , Semenov Victor V. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation

Arylnitromethanes were prepared by oxidation of aldoximes with sodium perborate or with urea hydrogen peroxide in the presence of boric acid. The use of urea hydrogen peroxide complex provides better and more stable yields of nitro compound and allows one to halve an acetic acid consumption. Only E-aldoximes are oxidized to arylnitromethanes while Z-isomers are transformed into complex mixtures not containing arylnitromethanes.

Maksimenko A.S. , Koblov I.A. , Chernysheva N.B. , Kislyi V.P. , Semenov V.V.
Convenient preparation of arylnitromethanes by oxidation of benzaldoximes with urea hydrogen peroxide
Mendeleev Communications. 2021. V.31. N6. P.818-820. DOI: 10.1016/j.mencom.2021.11.016 WOS Scopus OpenAlex

Web of science:	WOS:000731331600004
Scopus:	2-s2.0-85121753464
OpenAlex:	W4200235726

DB	Citing
OpenAlex	2
Scopus	2
Web of science	2