Successful Charge–Discharge Experiments of Anthraquinone-Bromate Flow Battery: First Report

Successful Charge–Discharge Experiments of Anthraquinone-Bromate Flow Battery: First Report Научная публикация

Журнал

Energies
ISSN: 1996-1073

Вых. Данные

Год: 2022, Том: 15, Номер: 21, Номер статьи : 7967, Страниц : DOI: 10.3390/en15217967

Авторы

Abunaeva Lilia ¹ , Kartashova Natalia ¹ , Karpenko Kirill ² , Chikin Dmitry ¹ , Verakso Darya ¹ , Loktionov Pavel ¹ , Pichugov Roman ¹ , Vereshchagin Anatoly ² , Petrov Mikhail ¹ , Antipov Anatoly ¹

Организации

1	EMCPS Department, Mendeleev University of Chemical Technology of Russia, 125047 Moscow, Russia
2	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russia

The proposed anthraquinone-bromate cell combines the advantages of anthraquinone-bromine redox flow batteries and novel hybrid hydrogen-bromate flow batteries. The anthraquinone-2,7-disulfonic acid is of interest as a promising organic negolyte due its high solubility, rapid kinetics of electrode reactions and suitable redox potentials combined with a high chemical stability during redox reactions. Lithium or sodium bromates as posolytes provide an anomalously high discharge current density of order ~A cm−2 due to a novel autocatalytic mechanism. Combining these two systems, we developed a single cell of novel anthraquinone-bromate flow battery, which showed a power density of 1.08 W cm−2, energy density of 16.1 W h L−1 and energy efficiency of 72% after 10 charge–discharge cycles.

Abunaeva L. , Kartashova N. , Karpenko K. , Chikin D. , Verakso D. , Loktionov P. , Pichugov R. , Vereshchagin A. , Petrov M. , Antipov A.
Successful Charge–Discharge Experiments of Anthraquinone-Bromate Flow Battery: First Report
Energies. 2022. V.15. N21. 7967 . DOI: 10.3390/en15217967 WOS Scopus OpenAlex

Web of science:	WOS:000881091500001
Scopus:	2-s2.0-85141863618
OpenAlex:	W4307434616

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OpenAlex	1
Web of science	2