Transition-metal-free trifluoromethylthiolation–acylation of arynes by insertion into the C–S bonds

Transition-metal-free trifluoromethylthiolation–acylation of arynes by insertion into the C–S bonds Full article

Journal

Green synthesis and catalysis
ISSN: 2666-5549

Output data

Year: 2021, Volume: 2, Number: 1, Pages: 62-65 Pages count : 4 DOI: 10.1016/j.gresc.2020.12.001

Authors

Cao Chengyao Kimmy ¹ , Tretyakov Evgeny ² , Chen Chao ^1,3

Affiliations

1	Key Laboratory of Bioorganic Phosphorus Chemistry & Chemical Biology (Ministry of Education), Department of Chemistry, Tsinghua University, Beijing 100084, China
2	N.D. Zelinsky Institute of Organic Chemistry, 47 Leninsky Prospect, Moscow 119991, Russia
3	State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Tianjin 300071, China

An efficient procedure to access to ortho-SCF3 substituted benzophenones from arynes and trifluoromethylthioesters has been developed under transition-metal free conditions. This difunctionalization process involves the first insertion of arynes into the C–S σ-bonds to achieve vicinal trifluoromethylthiolation-acylation of arenes in one step.

Cao C.K. , Tretyakov E. , Chen C.
Transition-metal-free trifluoromethylthiolation–acylation of arynes by insertion into the C–S bonds
Green synthesis and catalysis. 2021. V.2. N1. P.62-65. DOI: 10.1016/j.gresc.2020.12.001 OpenAlex

OpenAlex:

W3116073306

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