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The first example of anodic corrosion of Pd in aqueous ethylenediamine with formation of colloidal palladium Full article

Journal Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436
Output data Year: 2021, Volume: 31, Number: 5, Pages: 638-640 Pages count : 3 DOI: 10.1016/j.mencom.2021.09.015
Authors Vedenyapina Marina D. 1 , Kuznetsov Vladimir V. 1 , Kulaishin Stanislav A. 1 , Makhova Nina N. 1 , Kazakova Marina M. 1
Affiliations
1 N.D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991,Moscow, Russian Federation

Abstract: For the first time, corrosion of a Pd anode was detected during electrolysis in a weakly alkaline aqueous solution of ethylenediamine. The kinetics and mechanism of the process were investigated by the methods of cyclic voltammetry and gravimetry. Scanning electron microscopy showed corrosion of the Pd anode and deposition of Pd on the cathode surface, while the formation of colloidal Pd in the working solution was identified by transmission electron microscopy.
Cite: Vedenyapina M.D. , Kuznetsov V.V. , Kulaishin S.A. , Makhova N.N. , Kazakova M.M.
The first example of anodic corrosion of Pd in aqueous ethylenediamine with formation of colloidal palladium
Mendeleev Communications. 2021. V.31. N5. P.638-640. DOI: 10.1016/j.mencom.2021.09.015 WOS Scopus OpenAlex
Identifiers:
Web of science: WOS:000717972600015
Scopus: 2-s2.0-85119530571
OpenAlex: W3210537912
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