Stereoselective approach to conjugated enone oximes from aliphatic nitro compounds and sulfur ylides

Stereoselective approach to conjugated enone oximes from aliphatic nitro compounds and sulfur ylides Full article

Journal

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Output data

Year: 2021, Volume: 31, Number: 5, Pages: 686-689 Pages count : 4 DOI: 10.1016/j.mencom.2021.09.031

Authors

Akhmirov Rauf T. ^1,2 , Ioffe Sema L. ² , Sukhorukov Alexey Yu. ²

Affiliations

1	D. I. Mendeleev University of Chemical Technology of Russia, 125047 Moscow, Russian Federation
2	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation

A novel approach to conjugated enone oximes from aliphatic nitro compounds deals with double silylation of N,N-bis(silyloxy) enamines followed by a stereoselective reaction with an ester-stabilized sulfur ylide. The proposed mechanism involves the generation of labile nitrosoalkenes as intermediates, which react with the sulfur ylide to give target enone oximes.

Akhmirov R.T. , Ioffe S.L. , Sukhorukov A.Y.
Stereoselective approach to conjugated enone oximes from aliphatic nitro compounds and sulfur ylides
Mendeleev Communications. 2021. V.31. N5. P.686-689. DOI: 10.1016/j.mencom.2021.09.031 WOS Scopus OpenAlex

Web of science:	WOS:000717972600031
Scopus:	2-s2.0-85119519999
OpenAlex:	W3210583153

DB	Citing
OpenAlex	2
Scopus	2
Web of science	1