tert-Butyl Bis(4′-(Hexyloxy)-[1,1′-biphenyl]-4-yl)carbamate

tert-Butyl Bis(4′-(Hexyloxy)-[1,1′-biphenyl]-4-yl)carbamate Full article

Journal

Molbank
ISSN: 1422-8599

Output data

Year: 2021, Volume: 2021, Number: 3, Article number : M1247, Pages count : DOI: 10.3390/m1247

Authors

Chmovzh Timofey N. ^1,2 , Rakitin Oleg A. ^1,2

Affiliations

1	N.D. Zelinsky Institute of Organic Chemistry Russian Academy of Sciences, 47 Leninsky Prospekt, 119991 Moscow, Russia
2	Nanotechnology Education and Research Center, South Ural State University, 76 Lenina Avenue, 454080 Chelyabinsk, Russia

New donor building blocks, i.e., triarylamino derivatives, are of great interest for the production of organic photovoltaic materials. In this communication, bis(4′-(hexyloxy)-[1,1′-biphenyl]-4-yl)amine was synthesized in a two-step process via hydrolysis of its tert-butyl carbamate derivative. tert-Butyl bis(4′-(hexyloxy)-[1,1′-biphenyl]-4-yl)carbamate was obtained by Suzuki cross-coupling reaction of tert-butyl bis(4-bromophenyl)carbamate and (4-(hexyloxy)phenyl)boronic acid in the presence of tetrakis(triphenylphosphine)palladium(0). The structure of newly synthesized compounds was established by means of elemental analysis, high resolution mass-spectrometry, 1H, 13C-NMR, IR and UV spectroscopy and mass-spectrometry.

Chmovzh T.N. , Rakitin O.A.
tert-Butyl Bis(4′-(Hexyloxy)-[1,1′-biphenyl]-4-yl)carbamate
Molbank. 2021. V.2021. N3. M1247 . DOI: 10.3390/m1247 WOS Scopus OpenAlex

Web of science:	WOS:000699964100001
Scopus:	2-s2.0-85110487684
OpenAlex:	W3181866651

DB	Citing
OpenAlex	1
Scopus	1
Web of science	1