Photoredox-catalyzed silyldifluoromethylation of silyl enol ethers | Sciact

Photoredox-catalyzed silyldifluoromethylation of silyl enol ethers Научная публикация

Журнал

Beilstein Journal of Organic Chemistry
ISSN: 2195-951X , E-ISSN: 1860-5397

Вых. Данные

Год: 2020, Том: 16, Страницы: 1550-1553 Страниц : 4 DOI: 10.3762/bjoc.16.126

Авторы

Supranovich Vyacheslav I ¹ , Levin Vitalij V ¹ , Dilman Alexander D ¹

Организации

1	N. D. Zelinsky Institute of Organic Chemistry, Leninsky prosp. 47, 119991 Moscow, Russian Federation.

A method for the light-mediated fluoroalkylation of silyl enol ethers with (bromodifluoromethyl)trimethylsilane followed by a reduction of the primary products with sodium borohydride is described. An 18 W, 375 nm LED was used as the light source. The reaction is performed in the presence of a gold photocatalyst, which effects the generation of a (trimethylsilyl)difluoromethyl radical via cleavage of the carbon–bromine bond.

Supranovich V.I. , Levin V.V. , Dilman A.D.
Photoredox-catalyzed silyldifluoromethylation of silyl enol ethers
Beilstein Journal of Organic Chemistry. 2020. V.16. P.1550-1553. DOI: 10.3762/bjoc.16.126 WOS Scopus OpenAlex

Web of science:	WOS:000548344800001
Scopus:	2-s2.0-85090601454
OpenAlex:	W3039838571

БД	Цитирований
OpenAlex	4
Scopus	5
Web of science	5