Photoredox-catalyzed silyldifluoromethylation of silyl enol ethers Научная публикация
| Журнал |
Beilstein Journal of Organic Chemistry
ISSN: 2195-951X , E-ISSN: 1860-5397 |
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| Вых. Данные | Год: 2020, Том: 16, Страницы: 1550-1553 Страниц : 4 DOI: 10.3762/bjoc.16.126 | ||
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Реферат:
A method for the light-mediated fluoroalkylation of silyl enol ethers with (bromodifluoromethyl)trimethylsilane followed by a reduction of the primary products with sodium borohydride is described. An 18 W, 375 nm LED was used as the light source. The reaction is performed in the presence of a gold photocatalyst, which effects the generation of a (trimethylsilyl)difluoromethyl radical via cleavage of the carbon–bromine bond.
Библиографическая ссылка:
Supranovich V.I.
, Levin V.V.
, Dilman A.D.
Photoredox-catalyzed silyldifluoromethylation of silyl enol ethers
Beilstein Journal of Organic Chemistry. 2020. V.16. P.1550-1553. DOI: 10.3762/bjoc.16.126 WOS Scopus OpenAlex
Photoredox-catalyzed silyldifluoromethylation of silyl enol ethers
Beilstein Journal of Organic Chemistry. 2020. V.16. P.1550-1553. DOI: 10.3762/bjoc.16.126 WOS Scopus OpenAlex
Идентификаторы БД:
| Web of science: | WOS:000548344800001 |
| Scopus: | 2-s2.0-85090601454 |
| OpenAlex: | W3039838571 |