First example of peroxosolvate of iodine-containing organic molecule

First example of peroxosolvate of iodine-containing organic molecule Full article

Journal

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Output data

Year: 2021, Volume: 31, Number: 3, Pages: 352-355 Pages count : 4 DOI: 10.1016/j.mencom.2021.05.023

Authors

Churakov Andrei V. ¹ , Medved’ko Aleksei V. ² , Prikhodchenko Petr V. ¹ , Krut’ko Dmitry P. ³ , Vatsadze Sergey Z. ²

Affiliations

1	N. S. Kurnakov Institute of Inorganic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation
2	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation
3	Department of Chemistry, M. V. Lomonosov Moscow State University, 119991 Moscow, Russian Federation

Six new bispidine-based bis-amides containing residues of haloacetic acids were synthesized and characterized by X-ray crystallography. The dissolution of iodine-containing compound in concentrated hydrogen peroxide afforded bispidine peroxosolvate, in which the peroxide molecules participated in two donor hydrogen bonds with carbonyl oxygen atoms of the distinct adjacent organic molecules thus forming cyclic motifs in crystals. This structure is a first example of peroxosolvate of iodine-containing organic molecule.

Churakov A.V. , Medved’ko A.V. , Prikhodchenko P.V. , Krut’ko D.P. , Vatsadze S.Z.
First example of peroxosolvate of iodine-containing organic molecule
Mendeleev Communications. 2021. V.31. N3. P.352-355. DOI: 10.1016/j.mencom.2021.05.023 WOS OpenAlex

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