Light-mediated copper-catalyzed phosphorus/halogen exchange in 1,1-difluoroalkylphosphonium salts

Light-mediated copper-catalyzed phosphorus/halogen exchange in 1,1-difluoroalkylphosphonium salts Full article

Journal

Chemical Communications
ISSN: 1359-7345 , E-ISSN: 1364-548X

Output data

Year: 2019, Volume: 55, Number: 9, Pages: 1314-1317 Pages count : 4 DOI: 10.1039/c8cc09115c

Authors

Panferova Liubov I. ¹ , Levin Vitalij V. ¹ , Struchkova Marina I. ¹ , Dilman Alexander D. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Leninsky prosp. 47, 119991 Moscow, Russian Federation

A method for the assembly of the halodifluoromethyl group (CF2X, X = Cl, Br, I) is described. The reaction involves the light-mediated substitution of the triphenylphosphine by halide anions in readily accessible gem-difluorinated phosphonium salts.

Panferova L.I. , Levin V.V. , Struchkova M.I. , Dilman A.D.
Light-mediated copper-catalyzed phosphorus/halogen exchange in 1,1-difluoroalkylphosphonium salts
Chemical Communications. 2019. V.55. N9. P.1314-1317. DOI: 10.1039/c8cc09115c WOS Scopus OpenAlex

Web of science:	WOS:000458545700027
Scopus:	2-s2.0-85060504019
OpenAlex:	W2908082179

DB	Citing
OpenAlex	29
Scopus	27