Ammonium iodide-mediated electrosynthesis of unsymmetrical thiosulfonates from arenesulfonohydrazides and thiols

Ammonium iodide-mediated electrosynthesis of unsymmetrical thiosulfonates from arenesulfonohydrazides and thiols Full article

Journal

Mendeleev Communications
ISSN: 1364-551X , E-ISSN: 0959-9436

Output data

Year: 2019, Volume: 29, Number: 1, Pages: 80-82 Pages count : 3 DOI: 10.1016/j.mencom.2019.01.027

Authors

Terent’ev Alexander O. ^1,2 , Mulina Olga M. ¹ , Ilovaisky Alexey I. ¹ , Kokorekin Vladimir A. ^3,1 , Nikishin Gennady I. ¹

Affiliations

1	N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 119991 Moscow, Russian Federation
2	D. I. Mendeleev University of Chemical Technology of Russia, 125047 Moscow, Russian Federation
3	I. M. Sechenov First Moscow State Medical University, 119991 Moscow, Russian Federation

Unsymmetrical thiosulfonates were synthesized from thiols and arenesulfonohydrazides by their electrolysis in undivided cell equipped with graphite anode and stainless steel cathode under high current density applying NH4I both as a redox catalyst and a supporting electrolyte. In the course of the process, oxidative formation of S–S bond occurs with the loss of hydrazine moiety.

Terent’ev A.O. , Mulina O.M. , Ilovaisky A.I. , Kokorekin V.A. , Nikishin G.I.
Ammonium iodide-mediated electrosynthesis of unsymmetrical thiosulfonates from arenesulfonohydrazides and thiols
Mendeleev Communications. 2019. V.29. N1. P.80-82. DOI: 10.1016/j.mencom.2019.01.027 WOS Scopus OpenAlex

Web of science:	WOS:000460711400027
Scopus:	2-s2.0-85061618466
OpenAlex:	W2913732223

DB	Citing
OpenAlex	22
Scopus	20
Web of science	21